Intercalates of Vanadyl Phosphate with Unsaturated Alcohols

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F01%3A00004916" target="_blank" >RIV/60461373:22340/01:00004916 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Intercalates of Vanadyl Phosphate with Unsaturated Alcohols

Original language description

Intercalates of VOPO4 with several linear unsaturated alcohols (2-propen-1-ol, 2-buten-1-ol, 2-propyn-1-ol, 2-butyn-1-ol, 3-butyn-1-ol 2-pentyn-1-ol, 3-pentyn-1-ol, 4-pentyn-1-ol, 5-hexyn-1-ol, 2-octyn-1-ol, and 10-undecyn-1-ol) have been prepared and characterized by powder X-ray diffractometry, IR and Raman spectrometry, and thermogravimetry. The arrangement of the alcohol molecules with respect to the type and position of the multiple bonds in the carbon chain is proposed. Alcohols with terminal triple bonds form very stable intercalates. It is presumed that these alcohols are anchored to the host layers by donor-acceptor bonds between their oxygen atoms and the vanadium atoms of the host, and by H-bonding between the acetylenic hydrogen of the terminal carbon and the oxygen atoms of the host.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Journal of Inorganic Chemistry

ISSN

1438-1948

e-ISSN

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Volume of the periodical

Neuveden

Issue of the periodical within the volume

3

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

713-719

UT code for WoS article

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EID of the result in the Scopus database

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