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Transient behavior of an electrolytic diode

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F07%3A00017993" target="_blank" >RIV/60461373:22340/07:00017993 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Transient behavior of an electrolytic diode

  • Original language description

    The transient behavior of an electrolytic diode system was studied. A gel-like electrolytic diode was incorporated in a capillary microfluidic chip. The microfluidic platform guaranteed a constant composition of solutions on the diode boundaries. The current responses of the electrolytic diode to step-like changes of the imposed DC electric voltage were measured. Some of these transients were accompanied by a short-time overshoot of electric current density. In order to explain this phenomenon, a mathematical model of the electrolytic diode system was developed. Dynamical analysis of the model equations confirmed the existence of the electric current overshoots. Because the results of the experimental and the numerical transient studies were quite similar, we have explained the physical meaning of three selected overshoots by means of an analysis of the reaction-transport processes inside the electrolytic diode system. The transient experiments carried out in this study indicate that o

  • Czech name

    Transient behavior of an electrolytic diode

  • Czech description

    Bylo studováno transientní chování elektrolytické diody numericky i experimentálně. Byl vytvořen systém elektrolytické diody v mikrofluidním čipu. Experimentálně byly naměřeny volt-ampérové charakteristiky systému. Tyto charakteristiky byly doprovázeny krátkodobými překmity elektrického proudu. Tyto jevy byly poté studovány pomocí matematického model. Výsledky modelování a experimentů kvalitativně a do určité míry též kvantitativně souhlasí. Výsledky naznačují, že uvedený modelový koncept elektrolytickédiody je správný.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/1H-PK%2F24" target="_blank" >1H-PK/24: Microtechnology and nanotechnology in chemical, process and biological engineering: Methods of study of micro- and nano-structured materials and design of microchemical devices.</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    9

  • Issue of the periodical within the volume

    39

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    5374-5381

  • UT code for WoS article

  • EID of the result in the Scopus database