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Dynamical and stationary analysis of an electrolyte diode and comparison with experiments

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F06%3A00016653" target="_blank" >RIV/60461373:22340/06:00016653 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Dynamical and stationary analysis of an electrolyte diode and comparison with experiments

  • Original language description

    Stationary and non-stationary behavior of an electrolyte diode system is studied. The system consists of a microcapillary connecting two reservoirs with a strong acid and strong base. If an external electric field is imposed on the capillary, diode likecurrent-voltage characteristics is observed. A thin layer of electrolyte with extremely large pH gradient is formed in the closed regime of the diode. Transient behavior of the electrolyte diode is studied experimentally and numerically. Observed short-time overshoots of electric current in the current-voltage characteristics are explained based on numerical analysis of the reaction-transport processes in the capillary.

  • Czech name

    Dynamická a stacionární analýza elektrolytické diody a porovnání s experimenty

  • Czech description

    Stacionární a nestacionární chování elektrolytické diody bylo studováno. Byly vytvořeny voltampérové charakteristiky. Experimentálně pozorované krátkodobé překmity elektrického proudu během některých transientů jsou vysvětleny pomocí numerické analýzy studovaného systému.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F04%2F1442" target="_blank" >GA104/04/1442: Mass, heat and momentum transport in micro- and nano-structured ionic chemicaly reacting systems</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Computer-Aided Chemical Engineering

  • ISSN

    1570-7946

  • e-ISSN

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    A

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

    291-296

  • UT code for WoS article

  • EID of the result in the Scopus database