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Absolute Configuration and Conformational Analysis of Sesquiterpene Lactone Glycoside Studied by Vibrational Circular Dichroism Spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F07%3A00019314" target="_blank" >RIV/60461373:22340/07:00019314 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Absolute Configuration and Conformational Analysis of Sesquiterpene Lactone Glycoside Studied by Vibrational Circular Dichroism Spectroscopy

  • Original language description

    The absolute configuration of the guaiane-type sesquiterpene lactone 8-epiisolippidiol-3-O-b-D-glucopyranoside, isolated from plants of the genus Crepis, and the predominant solution-state conformation in CD3OD were determined by comparison of experimental and calculated VCD spectra. It has been found that the reported stereostructure of the compound corresponds to its absolute configuration.

  • Czech name

    Absolutní konfigurace a konformační analýza seskviterpenového lakton-glykosidu studovaná spektroskopií vibračního cirkulárního dichroismu

  • Czech description

    Absolutní konfigurace guayanového typu seskviterpenového laktonu izolovaného z rostlin rodu Crepis, 8-epiisolippidiol-3-O-b-D-glukopyranosidu, a jeho konformace převládající v CD3OD roztocích byly určeny porovnáváním experimentálních a vypočtených VCD spekter. Bylo zjištěno, že nalezená stereochemická struktura této sloučeniny odpovídá její absolutní konfiguraci.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Structure

  • ISSN

    0022-2860

  • e-ISSN

  • Volume of the periodical

    871

  • Issue of the periodical within the volume

    1-3

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

    67-72

  • UT code for WoS article

  • EID of the result in the Scopus database