Vibrational and Electronic Circular Dichroism Study of the Interactions of Cationic Porphyrins with (dG-dC)10 and (dA-dT)10

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F07%3A00019341" target="_blank" >RIV/60461373:22340/07:00019341 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Vibrational and Electronic Circular Dichroism Study of the Interactions of Cationic Porphyrins with (dG-dC)10 and (dA-dT)10

Original language description

The interactions of two different porphyrins, without axial ligands - 5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphyrin-Cu(II) tetrachloride (Cu(II)TMPyP) and with bulky meso substituents - 5,10,15,20-tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrintetrachloride (TMAP), with (dG-dC)10 and (dA-dT)10 were studied by combination of vibrational circular dichroism (VCD) and electronic circular dichroism (ECD) spectroscopy at different [oligonucleotide]/[porphyrin] ratios, where [oligonucleotide] and [porphyrin] are the concentrations of oligonucleotide per base-pair and porphyrin, respectively.

Czech name

Studium interakce katonických porphyrin s (dG-dC)10 a (dA-dT)10 metodami vibračního a elektronového cirkulárního dichroismu

Czech description

Kombinací elektronového a vibračního cirkulárního dichroismu byly studovánu interakce dvou různých porfyrinů (bez axiálního ligandu - 5,10,15,20-tetrakis(1-methylpyridinium-4-yl)porphyrin-Cu(II) tetrachlorid (Cu(II)TMPyP) a s objemnými mezosubstituemty -5,10,15,20-tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrin tetrachlorid (TMAP)) s (dG-dC)10 and (dA-dT)10 pro různé poměry [oligonukleotid]/[porphyrin], kde [oligonukleotid] a [porphyrin] jsou koncentrace oligonukleotidu vztažené na pár bází a porphyrinu.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CB - Analytical chemistry, separation

OECD FORD branch

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Project

<a href="/en/project/OC%20135" target="_blank" >OC 135: Detailed structural studies of bio-inspired compounds using advanced vibrational circular dichroism methods</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Biopolymers

ISSN

0006-3525

e-ISSN

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Volume of the periodical

85

Issue of the periodical within the volume

4

Country of publishing house

US - UNITED STATES

Number of pages

10

Pages from-to

349-358

UT code for WoS article

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EID of the result in the Scopus database

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