Partial molar volumes of organic solutes in water. XXIII. Cyclic ketones at temperatures T = 298 K to 573 K and pressures up to 30 MPa.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43884283" target="_blank" >RIV/60461373:22340/11:43884283 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jct.2011.02.010" target="_blank" >http://dx.doi.org/10.1016/j.jct.2011.02.010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jct.2011.02.010" target="_blank" >10.1016/j.jct.2011.02.010</a>

Result language
angličtina
Original language name
Partial molar volumes of organic solutes in water. XXIII. Cyclic ketones at temperatures T = 298 K to 573 K and pressures up to 30 MPa.
Original language description
Density data for dilute aqueous solutions of four cyclic ketones (cyclopentanone, cyclohexanone, cycloheptanone, and cyclohexane-1,4-dione) are presented together with standard molar volumes (partial molar volumes at infinite dilution) calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Experimental pressures were close to the saturated vapour pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Experimental standard molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function. Contributions of the molecular structural segments (methylene and carbonyl groups) to the standard molar volume were also evaluated and analyzed.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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