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ČeštinaEnglish

Partial molar volumes of organic solutes in water. XXII. Cyclic ethers at temperatures T = 298 K to 573 K and pressures up to 30 MPa.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023446" target="_blank" >RIV/60461373:22340/10:00023446 - isvavai.cz</a>

  • Result on the web

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  • DOI - Digital Object Identifier

    —

Alternative languages

  • Result language

    angličtina

  • Original language name

    Partial molar volumes of organic solutes in water. XXII. Cyclic ethers at temperatures T = 298 K to 573 K and pressures up to 30 MPa.

  • Original language description

    Density data for dilute aqueous solutions of five cyclic ethers (oxolane, 1,3-dioxolane, oxane, 1,4-dioxane, 1,3,5-trioxane) are presented together with partial molar volumes at infinite dilution calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Due to thermal decomposition the upper temperature limit was lower for 1,3-dioxolane (448 K) and 1,3,5-trioxane (498 K). Experimental pressures were close to the saturated vapour pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Experimental standard partial molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function and the semi-theoretical SOCW equation of state. Contributions of the group contribution method proposed previously were also evaluated and analyzed.

  • Czech name

    —

  • Czech description

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Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BJ - Thermodynamics

  • OECD FORD branch

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Result continuities

  • Project

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  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical Thermodynamics

  • ISSN

    0021-9614

  • e-ISSN

    —

  • Volume of the periodical

    42

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    11

  • Pages from-to

    —

  • UT code for WoS article

    000275575100011

  • EID of the result in the Scopus database

    —

Similar results(10)

Partial molar volumes of organic solutes in water. XXI. Cyclic ethers at temperatures T = 278 K to 373 K and at low pressure.Partial Molar Isentropic Compressions of Selected Cyclic Ethers at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure.Partial molar volumes of organic solutes in water. XXIII. Cyclic ketones at temperatures T = 298 K to 573 K and pressures up to 30 MPa.