In-Flight Epimerization of a Bis-Troger Base

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43891623" target="_blank" >RIV/60461373:22340/11:43891623 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/11:00363662
Result on the web
<a href="http://dx.doi.org/10.1002/anie.201007162" target="_blank" >http://dx.doi.org/10.1002/anie.201007162</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201007162" target="_blank" >10.1002/anie.201007162</a>

Result language
angličtina
Original language name
In-Flight Epimerization of a Bis-Troger Base
Original language description
In 1887, Julius Tröger reported the synthesis of a nitrogen base,1 whose structure was determined only about 50 years later.2 In "Tröger bases", nitrogen atoms serve as chiral centers because the otherwise rapid nitrogen inversion is prevented by conformational strain. After Prelog and Wieland separated the enantiomers,3 the chirality and the rigid V-shape of Tröger bases led to widespread applications in chemistry.4 A fundamental question in the chemistry of Tröger bases concerns the mechanism of theirpseudo-epimerization,5 for which either a proton-catalyzed ring opening or a retro-Diels-Alder (RDA) sequence has been proposed (Scheme 1).6
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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