Anion complexation by calix[4]arene-TTF conjugates

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F12%3A43871506" target="_blank" >RIV/60461373:22340/12:43871506 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/12:00367786 RIV/60461373:22310/12:43871506
Result on the web
<a href="http://dx.doi.org/10.1016/j.dyepig.2011.06.001" target="_blank" >http://dx.doi.org/10.1016/j.dyepig.2011.06.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.dyepig.2011.06.001" target="_blank" >10.1016/j.dyepig.2011.06.001</a>

Result language
angličtina
Original language name
Anion complexation by calix[4]arene-TTF conjugates
Original language description
Calix[4]arenes bearing tetrathiafulvalene (TTF) moieties appended to the upper rim via the amidic functions were synthesized and used for 1H NMR and UV/Vis complexation studies towards selected anions. It was found that the complexation affinity towards(H2PO4-) dramatically depends on the substitution pattern of the calixarene moiety. As a result, the proximally disubstituted derivative has a complexation constant by two orders of magnitude higher than the distally disubstituted analogue. The differences between proximal and distal receptors were also documented by their behaviour during the oxidation of the attached TTF units.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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