Geometry and Microwave Rotational Spectrum of the (FCOO center dot)-O-16-O-18 Radical

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895265" target="_blank" >RIV/60461373:22340/13:43895265 - isvavai.cz</a>
Result on the web
<a href="http://pubs.acs.org/doi/ipdf/10.1021/jp4054549" target="_blank" >http://pubs.acs.org/doi/ipdf/10.1021/jp4054549</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jp4054549" target="_blank" >10.1021/jp4054549</a>

Result language
angličtina
Original language name
Geometry and Microwave Rotational Spectrum of the (FCOO center dot)-O-16-O-18 Radical
Original language description
The rotational spectrum of an asymmetrically substituted isotopologue of the fluoroformyloxyl radical (FCOO center dot)-O-16-O-18 with resolved fine and hyperfine structures were measured and analyzed for the very first time The molecular parameters of this radical obtained from the spectral analysis were processed along with the symmetrical isotopologues (FCO2 center dot)-O-16 and (FCO2 center dot)-O-18 and accurate substitution geometry was attained. In addition to those, coupled cluster quantum chemistry calculations were Used to scale the experimental parameters, and in this manner, trustworthy values of the equilibrium and ground state geometries were derived.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
S - Specificky vyzkum na vysokych skolach

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)