Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00314669" target="_blank" >RIV/61388955:_____/08:00314669 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22340/08:00020232
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot
Original language description
More than 160 new hyperfine components of rotational transitions of the free fluoroformyloxyl radical FCO2 center dot have been measured using the Prague millimeter wave high resolution spectrometer. The frequencies of these transitions together with thepreviously measured data were analyzed in detail and precise values of magnetic hyperfine and fine parameters were obtained. These new parameters significantly improve the values of previously determined hyperfine parameters which were rather unreliable. The new fine and hyperfine parameters obtained in this study are compatible with those of the simultaneously electron paramagnetic resonance study. Besides that, significantly improved ground state rotational and centrifugal distortion constants of thefluoroformyloxyl radical were derived. (C) 2008 American Institute of Physics.
Czech name
Detailní studie jemných a hyperjemných struktur rotačního spektra volného fluoroformyloxylového radikálu FCO2
Czech description
Více jak 160 nových hyperjemných komponent rotačních přechodů volného fluoroformyloxylového radikálu FCO2. bylo změřeno pražským vysoce rozlišeným spektrometrem v milimetrové oblasti. Frekvence těchto přechodů společně s dostupnými měřenými daty byly analyzovány a byly určeny přesné hodnoty magnetických hyperjemných a jemných parametrů.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Physics
ISSN
0021-9606
e-ISSN
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Volume of the periodical
128
Issue of the periodical within the volume
22
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
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UT code for WoS article
000256706300011
EID of the result in the Scopus database
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