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Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895524" target="_blank" >RIV/60461373:22340/13:43895524 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.ces.2012.01.003" target="_blank" >http://dx.doi.org/10.1016/j.ces.2012.01.003</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ces.2012.01.003" target="_blank" >10.1016/j.ces.2012.01.003</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid

  • Original language description

    Sodium dodecyl-benzenesulfonate is an industrially important anionic surfactant, used in detergent powders and other cleaning products. It is produced by the neutralisation of dodecyl-benzenesulfonic acid with a liquid or a solid base. In the latter case, called dry neutralisation, the acid simultaneously acts as a granulation binder and the reaction kinetics determine not only the overall conversion but also the properties of the formed granules. In this work, the measurement of the kinetics of dry neutralisation using a laboratory-scale mechanically agitated granulator is described. The volume of evolved CO2, which is a by-product of the reaction, has been recorded as a function of time for several temperatures and agitation rates. A mathematical model of the process has been formulated and used in conjunction with experimental data to calculate the reaction rate as a function of operating parameters.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemical Engineering Science

  • ISSN

    0009-2509

  • e-ISSN

  • Volume of the periodical

    86

  • Issue of the periodical within the volume

    4 February 2013

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    2-8

  • UT code for WoS article

    000311431800002

  • EID of the result in the Scopus database