Synthesis and Characterization of a Helicene-Based Imidazolium Salt and Its Application in Organic Molecular Electronics

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43900050" target="_blank" >RIV/60461373:22340/15:43900050 - isvavai.cz</a>

Alternative codes found

RIV/00216275:25310/14:39899040 RIV/68378271:_____/15:00440909 RIV/67985858:_____/15:00440909 RIV/61989592:15310/15:33155895 RIV/61989592:15110/15:33155895

Result on the web

<a href="http://onlinelibrary.wiley.com/doi/10.1002/chem.201405239/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/chem.201405239/full</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/chem.201405239" target="_blank" >10.1002/chem.201405239</a>

Result language

angličtina

Original language name

Synthesis and Characterization of a Helicene-Based Imidazolium Salt and Its Application in Organic Molecular Electronics

Original language description

Herein we demonstrate the synthesis of a helicene-based imidazolium salt. The salt was prepared by starting from racemic 2-methyl[6]helicene, which undergoes radical bromination to yield 2-(bromomethyl)[6]helicene. Subsequent treatment with 1-butylimidazole leads to the corresponding salt 1-butyl-3-(2-methyl[6]helicenyl)-imidazolium bromide. The prepared salt was subsequently characterized by using NMR spectroscopy and X-ray analysis, various optical spectrometric techniques, and computational chemistry tools. Finally, the imidazolium salt was immobilized onto a SiO2 substrate as a crystalline or amorphous deposit. The deposited layers were used for the development of organic molecular semiconductor devices and the construction of a fully reversible humidity sensor.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemistry A European Journal

ISSN

0947-6539

e-ISSN

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Volume of the periodical

21

Issue of the periodical within the volume

6

Country of publishing house

DE - GERMANY

Number of pages

5

Pages from-to

2343-2347

UT code for WoS article

000348510400009

EID of the result in the Scopus database

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