Vapor pressures and thermophysical properties of selected hexenols and recommended vapor pressure for hexan-1-ol

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43900275" target="_blank" >RIV/60461373:22340/15:43900275 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/15:00464699
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0378381215002794" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0378381215002794</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.fluid.2015.05.026" target="_blank" >10.1016/j.fluid.2015.05.026</a>

Result language
angličtina
Original language name
Vapor pressures and thermophysical properties of selected hexenols and recommended vapor pressure for hexan-1-ol
Original language description
A thermodynamic study of selected unsaturated alcohols, cis-hex-3-en-1-ol, trans-hex-2-en-1-ol, and hex-1-en-3-ol, together with hexan-1-ol, is presented in this work. The vapor pressure measurements were performed using the static method over the environmentally important temperature range from 238 to 308 K. Liquid heat capacities were measured by Tian-Calvet calorimetry in the temperature interval from 258 to 355 K and were extended by controlled extrapolation by differential scanning calorimetry (DSC) toward the normal boiling point temperatures. The phase behavior was investigated by DSC from 183 K. The thermodynamic properties in the ideal-gas state were calculated by combining statistical thermodynamics and density functional theory (DFT) calculations. Scaling factors were evaluated based on measured Raman and IR spectra. Calculated ideal-gas heat capacities and experimental data on vapor pressures, condensed phase heat capacities, and vaporization enthalpies were treated simulta
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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