Use of Phase Transition Curves for Testing Models of the pH-Oscillatory Hydrogen Peroxide-Thiosulfate-Sulfite Reaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F16%3A43903023" target="_blank" >RIV/60461373:22340/16:43903023 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/acs.jpcb.6b00441" target="_blank" >http://dx.doi.org/10.1021/acs.jpcb.6b00441</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpcb.6b00441" target="_blank" >10.1021/acs.jpcb.6b00441</a>

Result language
angličtina
Original language name
Use of Phase Transition Curves for Testing Models of the pH-Oscillatory Hydrogen Peroxide-Thiosulfate-Sulfite Reaction
Original language description
The reaction system hydrogen peroxide-thiosulfate-sulfite in diluted sulfuric acid (HPTS) displays strongly nonlinear dynamics when operated in a continuous-flow stirred tank reactor. Due to a crucial role of hydrogen ion during the reaction, this system is a prime example of an inorganic pH-oscillator. Under specific external conditions the system exhibits multiple steady states, periodic oscillations and chaotic behavior. We focus valuating alternative kinetic models by exploring phase resetting of the periodic oscillatory regime caused by a single-pulse perturbation with various reacting species. Phase transition curve (PTC), the plot of phase after the resetting against the phase of perturbation, is a convenient characteristic of the oscillatory dynamics adopted as a major tool in this work. Experimental results for hydrogen ions, hydroxide ions, thiosulfate ions, sulfite ions, and hydrogen sulfite ions used as perturbants are systematically compared with calculations under corresponding conditions using two available reaction mechanisms. In addition, we use the stoichiometric network analysis to identify possible core oscillatory subnetworks in the models and choose the one that corresponds best to the measured PTCs.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
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Project
<a href="/en/project/GA15-17367S" target="_blank" >GA15-17367S: Dynamics of complex reaction networks in enzyme reactors and photobioreactors</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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