Rotational spectra of hydrazoic acid

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43915173" target="_blank" >RIV/60461373:22340/17:43915173 - isvavai.cz</a>
Result on the web
<a href="https://ac.els-cdn.com/S0022285217300036/1-s2.0-S0022285217300036-main.pdf?_tid=spdf-94882c3d-cc81-4bbd-8270-1014376b8331&acdnat=1519811185_7d79dae62e8d59349b32340136b28fb5" target="_blank" >https://ac.els-cdn.com/S0022285217300036/1-s2.0-S0022285217300036-main.pdf?_tid=spdf-94882c3d-cc81-4bbd-8270-1014376b8331&acdnat=1519811185_7d79dae62e8d59349b32340136b28fb5</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jms.2017.04.002" target="_blank" >10.1016/j.jms.2017.04.002</a>

Result language
angličtina
Original language name
Rotational spectra of hydrazoic acid
Original language description
Hydrazoic acid is a quasi-linear molecule with typical strong perturbations among rotational levels in different vibrationally excited states. The rovibrational interactions among the ground and the two lowest vibrationally excited states v(5) and v(6) make the line assignments very complicated. Overall 446 new rotational transitions were measured and assigned to rovibrational quantum numbers. This new dataset contains 194 transitions from the ground state, 160 and 92 transitions from the vibrationally excited v(s) and v(6) states, respectively. The rotational data set is extended up to K-a = 8 for the ground state, K-a = 7 for v(5), and Ka = 3 for vs. The frequencies of these new rotational lines, along with the data from previous sub millimetre and infrared studies were quantitatively analysed. The level crossings among ground and vibrationally excited v(5) and v(6) states and the corresponding rovibrational interactions were described in detail. (C) 2017 Elsevier Inc. All rights reserved.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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