Arylation of thiacalix[4]arenes using organomercurial intermediates

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22810%2F16%3A43902658" target="_blank" >RIV/60461373:22810/16:43902658 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/16:43902658
Result on the web
<a href="http://dx.doi.org/10.1039/c5nj02427g" target="_blank" >http://dx.doi.org/10.1039/c5nj02427g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5nj02427g" target="_blank" >10.1039/c5nj02427g</a>

Result language
angličtina
Original language name
Arylation of thiacalix[4]arenes using organomercurial intermediates
Original language description
Direct mercuration of thiacalixfzilarenes immobilized in the cone or 1,3-alternate conformations followed by Pd-catalyzed arytation was applied to achieve either meta- or para-substitution of basic skeletons. The arylated products represent unique substitution patterns in thiacalixarene chemistry and their conformational behaviour was studied using a combination of dynamic NMR techniques and X-ray crystallography. The usefulness of organomercurial intermediates was also demonstrated through the preparation of thiacatix[4]arene dimers so far unknown in thiacalixarene chemistry.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F12%2F2027" target="_blank" >GAP207/12/2027: Synthesis and applications of inherently chiral calixarenes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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