Crystal Structures of Unusual Titanocene By-Products from Attempted Dimerization of Terminal Alkynes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F00%3A54000142" target="_blank" >RIV/61388955:_____/00:54000142 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Crystal Structures of Unusual Titanocene By-Products from Attempted Dimerization of Terminal Alkynes.

Original language description

Structures of unusual organometallic products -[(1,2,3,3a,7a-):(3a,4,5,6,7,7a-)-4,7-bis(trimethylsilyl)indenyl]-di--hydrobis[(-cyclopentadienyl)titanium(Ti(III)/Ti(II)] and -[(3,4,5-)-(E,E)-2,2,7,7,-tetramethylocta-3,5-diene]bis[bis (-methylcyclopentadienyl)titanium] were determined by X-ray diffraction analysis. The compounds arose as by-products in very low yields in the Ti(C 5 H 5 ) 2 (Me 3 SiC CSiMe 3 )-HCCSiMe 3 and Ti(C 5 H 4 Me) 2 (Me 3 SiC CSiMe 3 )systems, respectively, when exposed to sunlight.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2000

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Collection of Czechoslovak Chemical Communications

ISSN

0010-0765

e-ISSN

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Volume of the periodical

65

Issue of the periodical within the volume

9

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

14

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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