Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems [(.eta. 5 -C 5 Me 5 )M(.mu.-L)M(.eta. 5 -C 5 Me 5 )] + (M=Rh, Ir; L=2,5-diiminopyrazines) in Relation to the Radicals [(.eta. 5 -C 5 Me 5 )CIM (.m

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F00%3A54000213" target="_blank" >RIV/61388955:_____/00:54000213 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems [(.eta. 5 -C 5 Me 5 )M(.mu.-L)M(.eta. 5 -C 5 Me 5 )] + (M=Rh, Ir; L=2,5-diiminopyrazines) in Relation to the Radicals [(.eta. 5 -C 5 Me 5 )CIM (.m
Original language description
Electrochemical reduction of the dinuclear ions proceeds via paramagnetic intermediates with considerable metal participation at the singly occupied MO.The main difference between bpip[2,5-bis(1-phenyliminoethyl)pyrazine) and bxip(2,5-bis[1-(2,6-dimethylphenyl)iminiethyl]pyrazine) systems is destabilization of the chloride-containing forms throught the bxip ligand for reason of steric interference.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Project
<a href="/en/project/OC%20D15.10" target="_blank" >OC D15.10: Electrochemistry of nano-structures at heterogeneous interfaces: formation, properties and electron transfer reactions.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2000
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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