Synthesis and Crystal Structures of Dimethylsilylene-Bridged (Amidocyclopentadienyl)Dichlorotitanium(IV) Complexes with Various Substituents on the Cyclopentadienyl Ligand.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010075" target="_blank" >RIV/61388955:_____/01:54010075 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Synthesis and Crystal Structures of Dimethylsilylene-Bridged (Amidocyclopentadienyl)Dichlorotitanium(IV) Complexes with Various Substituents on the Cyclopentadienyl Ligand.
Original language description
(Amidocyclopentadienyl)dichlorotitanium(IV) complexes of the general formula [TiCl2{.eta.5:.eta.1 (N)-C5(1-SiMe2Nt-Bu-2,3,4-Me3-5-R)}], where R=H (6b), Ph (6c), 4-fluorophenyl (6d), and 1-methylallyl (6e) were synthesized and characterized by spectral methods. Solid-state structure of [TiCl2{.eta.5:.eta.1 (N)-C5Me4(SiMe2Nt-Bu)}] (6a) and 6d determined by single-crystal X-ray diffraction showed that variation of the ring substituent R has only a negligible effect on the molecular structure of the complexes.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/IBS4040017" target="_blank" >IBS4040017: Metallocene catalysts anchored on mesoporous support of the MCM-41 type</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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