Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F01%3A00107027" target="_blank" >RIV/00216208:11310/01:00107027 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands

Original language description

(Amidocyclopentadienyl)dichlorotitanium(IV) complexes of the general formula, [TiCl2{h5:h1(N)-C5(1-SiMe2Nt-Bu-2,3,4-Me3-5-R)}], where R = H (6b), Ph (6c), 4-fluorophenyl (6d) and 1-methylallyl (6e) were synthesized and characterized by spectral methods.Solid-state structure of [TiCl2{h5:h1(N)-C5Me4(SiMe2Nt-Bu)}] (6a) and 6d determined by single-crystal X-ray diffraction showed th at variation of the ring substituent R has only a negligible effect(6a) and 6d determined by single-crystal X-ray diffraction showed that variation of the ring substituent R has only a negligible effect on the molecular structure of the complexes.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Collection of Czechoslovak Chemical Communications

ISSN

0010-0765

e-ISSN

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Volume of the periodical

66

Issue of the periodical within the volume

4

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

6

Pages from-to

605-610

UT code for WoS article

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EID of the result in the Scopus database

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