Synthesis of {1,3-Bis(.eta. 5 -tetramethylcyclopetadienyl)-1,1,3,3-tetramethyldisiloxane}dichlorotitanium(IV) via Hydrolysis of Bis{.eta. 5 -(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV).

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010155" target="_blank" >RIV/61388955:_____/01:54010155 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Synthesis of {1,3-Bis(.eta. 5 -tetramethylcyclopetadienyl)-1,1,3,3-tetramethyldisiloxane}dichlorotitanium(IV) via Hydrolysis of Bis{.eta. 5 -(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV).
Original language description
Bis{eta5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{eta5-C5Me4(SiMe2NMe2)}2] (1), easily undergoes hydrolytic cleavage of the Si-N bonds to give dimethylamine and {1,3-bis(eta5-tetramethylcyclopentadienyl)-1,1,3,3-tetramethyldisiloxane}dichlorotitanium(IV), ansa-[TiCl2{(eta5-C5Me4SiMe2)2O}] (2), in almost quantitative yields. The crystal structures of compounds 1 and 2 were determined by single-crystal X-ray diffraction.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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