Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F04%3A00107575" target="_blank" >RIV/61388955:_____/04:00107575 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV)
Original language description
Bis{.eta.5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{.eta.5-C5Me4(SiMe2NMe2)}2] (1), reacts with sulfane under cleavage of both Si-N and Ti-Cl bonds to give sulfido-tethered titanocene compound bis{.eta.5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-.kappa.S)cyclopentadienyl}titanium(IV), [Ti{.eta.5-C5Me4(SiMe2S-.kappa.S)}2] (4), and dimethylamine hydrochloride as the byproduct. The crystal structure of compound 4 has been determined by single-crystal X-raydiffraction.
Czech name
Syntéza a struktura bis{?5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-?S) cyklopentadienyl}titanového(IV) komplexu
Czech description
Bis{?5-(N,N-dimethylaminodimethylsilyl) tetramethylcyklopentadienyl}dichlorotitan(IV), [TiCl2{?5-C5Me4(SiMe2NMe2)}2] (1), reaguje se sulfanem štěpením obou Si-N a Ti-Cl vazeb za vzniku sulfido-vázané titanocenové sloučeniny bis{?5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-?S) cyklopentadienyl}titan(IV), [Ti{?5-C5Me4(SiMe2S-?S)}2] (4), a dimethylamin hydrochloridu jako vedlejšího produktu. Krystalová struktura 4 byla určena rentgenostrukturní analýzou.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
<a href="/en/project/GA203%2F02%2F0774" target="_blank" >GA203/02/0774: Silicon-based ansa-titanocene complexes - synthesis, properties and catalytic activities</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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