Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex [(.eta. 5 -C 5 Me 5 )CIRh(.mu.-bptz)Re(CO) 3 Cl](PF 6 ), bptz=3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010185" target="_blank" >RIV/61388955:_____/01:54010185 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex [(.eta. 5 -C 5 Me 5 )CIRh(.mu.-bptz)Re(CO) 3 Cl](PF 6 ), bptz=3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine.

Original language description

Investigated heterodinuclear complex contains centers which are known to engage in hydride transfer catalysis (Rh) or in CO2 activation (Re). The compound was structurally characterized. Spectroelectrochemistry revealed an electrochemically reversible one-electron uptake by the bptz bridge a rhodium chloride-dissociative second reduction to yield neutral [(C5Me5)Rh(bptz)Re(CO)3, and quasi-reversible third one-electron reduction.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/OC%20D14.20" target="_blank" >OC D14.20: Oganometallic and Metallo-organic Building Blocks for Photonic Materials</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

9

Country of publishing house

US - UNITED STATES

Number of pages

5

Pages from-to

1437-1441

UT code for WoS article

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EID of the result in the Scopus database

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