Rhenium(I) Coordinated Lumazine and Pterin Derivatives: Structure and Spectroelectrochemistry of Reversible Reducible (6-ATML)Re(CO 3 Cl (6-ATML=6-acetyl-1,3,7-trimethyllumazine).

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010205" target="_blank" >RIV/61388955:_____/01:54010205 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Rhenium(I) Coordinated Lumazine and Pterin Derivatives: Structure and Spectroelectrochemistry of Reversible Reducible (6-ATML)Re(CO 3 Cl (6-ATML=6-acetyl-1,3,7-trimethyllumazine).

Original language description

Complexes between substituted lumazines or pterins and Re(CO)3Cl were synthesized and characterized crystallographically, electrochemically and spectroscopically. The acetyl acceptor substituent facilitates the reversible one-electron reduction to a persistent anion radical complex [(6-ATML)Re(CO)3Cl]- which is accompanied by variable low-frequency shifts of the six carbonyl stretching bands and by the appearance of a broad EPR signal.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/OC%20D15.10" target="_blank" >OC D15.10: Electrochemistry of nano-structures at heterogeneous interfaces: formation, properties and electron transfer reactions.</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

325

Issue of the periodical within the volume

1

Country of publishing house

CH - SWITZERLAND

Number of pages

8

Pages from-to

65-72

UT code for WoS article

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EID of the result in the Scopus database

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