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Kinetics of Oxidative Dehydrogenation of Isobutyric Acid over K 2 HPMo 12 O 40 Catalyst.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010258" target="_blank" >RIV/61388955:_____/01:54010258 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Kinetics of Oxidative Dehydrogenation of Isobutyric Acid over K 2 HPMo 12 O 40 Catalyst.

  • Original language description

    The kinetics of oxidative dehydrogenation of isobutyric acid has been studied in gas phase over the K2HPMo12O40 catalysts. The rate of consumption of isobutyric acid and of formation of methacrylic acid and acetone depending of the degree of conversion of isobutyric acid indicated an autocatalytic reaction mechanism. A model of MoVI-O-MoV site has been suggested and the autocatalytic process to be due to formation of this site.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F98%2F0172" target="_blank" >GA104/98/0172: Catalytic oxidation of C3 and C4 aldehydes to organic acids</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2001

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    66

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    13

  • Pages from-to

    575-587

  • UT code for WoS article

  • EID of the result in the Scopus database