The Rotational Spectrum of SiHF3 in the Vibrational State v(6)=2: Observation of Direct /-Type Resonance Transitions.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020254" target="_blank" >RIV/61388955:_____/02:54020254 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The Rotational Spectrum of SiHF3 in the Vibrational State v(6)=2: Observation of Direct /-Type Resonance Transitions.
Original language description
The v(6) = 2 vibrational state of the main isotopomer of trifluorosilane, (SiHF3)-Si-28, has been investigated in the centimeter- and millimeter-wave ranges. Rotational spectra following the DeltaJ = 1, Deltak = Deltal = 0 selection rule have been measured up to J = 24 and K = 23 and for both values of l. Two types of direct l-type resonance transitions induced by the (Deltal = Deltak = +/-2) interaction could be observed by means of waveguide Fourier transform microwave spectroscopy in the range 8-26 GHz: 252 transitions following the DeltaJ = 0, Deltal = Deltak = +/-2 selection rule covering values of J = 7-39 and G = k - l from 1 to 18 and 90 transitions following the DeltaJ = 0, Deltal = Deltak = +/-4 selection rule covering values of J = 17-52 andG from 1 to 4. Due to the strong (2,2) resonance, 18 A(1)-A(2) splittings of the k = l = +/-2 states from J = 36-53 could also be observed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F01%2F1274" target="_blank" >GA203/01/1274: High-resolution molecular spectroscopy (with aspects in molecular physics, energy transfer, remote sensing of atmospheric pollutants, and metrology)</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Spectroscopy
ISSN
0022-2852
e-ISSN
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Volume of the periodical
216
Issue of the periodical within the volume
N/A
Country of publishing house
US - UNITED STATES
Number of pages
12
Pages from-to
481-492
UT code for WoS article
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EID of the result in the Scopus database
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