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The Rotational Spectrum of SiHF3 in the Vibrational State v(6)=2: Observation of Direct /-Type Resonance Transitions.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020254" target="_blank" >RIV/61388955:_____/02:54020254 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The Rotational Spectrum of SiHF3 in the Vibrational State v(6)=2: Observation of Direct /-Type Resonance Transitions.

  • Original language description

    The v(6) = 2 vibrational state of the main isotopomer of trifluorosilane, (SiHF3)-Si-28, has been investigated in the centimeter- and millimeter-wave ranges. Rotational spectra following the DeltaJ = 1, Deltak = Deltal = 0 selection rule have been measured up to J = 24 and K = 23 and for both values of l. Two types of direct l-type resonance transitions induced by the (Deltal = Deltak = +/-2) interaction could be observed by means of waveguide Fourier transform microwave spectroscopy in the range 8-26 GHz: 252 transitions following the DeltaJ = 0, Deltal = Deltak = +/-2 selection rule covering values of J = 7-39 and G = k - l from 1 to 18 and 90 transitions following the DeltaJ = 0, Deltal = Deltak = +/-4 selection rule covering values of J = 17-52 andG from 1 to 4. Due to the strong (2,2) resonance, 18 A(1)-A(2) splittings of the k = l = +/-2 states from J = 36-53 could also be observed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F01%2F1274" target="_blank" >GA203/01/1274: High-resolution molecular spectroscopy (with aspects in molecular physics, energy transfer, remote sensing of atmospheric pollutants, and metrology)</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Spectroscopy

  • ISSN

    0022-2852

  • e-ISSN

  • Volume of the periodical

    216

  • Issue of the periodical within the volume

    N/A

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

    481-492

  • UT code for WoS article

  • EID of the result in the Scopus database