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Rotational Spectrum of NSF3 in the Ground and v(5)=1 Vibrational States: Observation of Q-Branch Perturbation-Allowed Transitions with Delta(k-l)=0, +/- 3, +/- 6 and Anomalies in the Rovibrational Structure of the v(5)=1 State

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F09%3A00336519" target="_blank" >RIV/61388955:_____/09:00336519 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Rotational Spectrum of NSF3 in the Ground and v(5)=1 Vibrational States: Observation of Q-Branch Perturbation-Allowed Transitions with Delta(k-l)=0, +/- 3, +/- 6 and Anomalies in the Rovibrational Structure of the v(5)=1 State

  • Original language description

    The rotational spectrum of NSF3 in the ground and v(5) = 1 vibrational states has been investigated in the centimeter- and millimeter-wave ranges. R-branch (J + 1 <- J) transitions for J = 0, 1 and Q-branch rotational transitions for the v(5) = 1 vibrational state have been measured by waveguide Fourier transform microwave spectroscopy in the range 8-26.5 GHz. The Q-branch transitions include 28 direct l-type doubling transitions (kl = +1, A(1)) <-> (kl = +1, A(2)) with J <= 62, and 108 direct l-type resonance transitions following the selection rule Delta k = Delta l = +/- 2 with J <= 60 and G = lk - l vertical bar <= 3. A process called "regional resonance" was observed in which a cluster of levels interacted strongly over a large range in J.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physical Chemistry A

  • ISSN

    1089-5639

  • e-ISSN

  • Volume of the periodical

    113

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

  • UT code for WoS article

    000262665300006

  • EID of the result in the Scopus database