The Copper(I) / Copper(II) Transition in Complexes with 8-alkylthioquinoline Based Multidentate Ligands.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030107" target="_blank" >RIV/61388955:_____/03:54030107 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
The Copper(I) / Copper(II) Transition in Complexes with 8-alkylthioquinoline Based Multidentate Ligands.
Original language description
Three linear multidentate ligands incorporating terminal 8-thioquinoline rings and flexible polyethylene glycol or semi-rigid o-xylylene spacers have been synthesised: pentadentate 1,5-bis(8-quinolylsulfanyl)-3-oxapentane (OESQ), hexadentate 1,8-bis(8-quinolylsulfanyl)-3,6-dioxaoctane (ODSQ) and tetradentate 1,2-bis(quinolin-8-ylsulfanyl-methyl)benzene (OBSQ). Reaction of these ligands with various copper salts afforded three families of copper(I) and copper(II) complexes with the general formula [Cu(L1)(L2)]Xm,: L1 = OESQ and L2/Xm = H2O/(BF4- )2 4, DMF/(BF4- )2 5, H2O/(ClO4-)2 6, NO3-/ NO3- 7, NO3-/ ClO4- 8, none/ BF4- 9; L1 = ODSQ and L2/Xm = none/(BF4- )2 10, none/(ClO4-)2 11, none/(NO3-)2 12, none/Cu(NO3)42- 13, none/ClO4- 14; L1 = OBSQ and L2/Xm= ClO4-/ClO4- 15, H2O/(BF4- )2 16, DMF/(ClO4-)2 17, DMF/(BF4- )2 18, NO3-/ NO3- 19, H2O/( NO3-)2 20, DMSO/(ClO4-)2 21, NO3-/BF4- 22, none/BF4- 23. For comparison, three copper complexes [Cu(EtSQ)2(ClO4)2] 1, [Cu(EtSQ)2] (ClO4) 2.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/OC%20D15.10" target="_blank" >OC D15.10: Electrochemistry of nano-structures at heterogeneous interfaces: formation, properties and electron transfer reactions.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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