Solvent Influence on Photochemistry of Small Biomolecules in Clusters
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00341709" target="_blank" >RIV/61388955:_____/08:00341709 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Solvent Influence on Photochemistry of Small Biomolecules in Clusters
Original language description
We present a photolysis study of pyrrole, imidazole and pyrazole clusters in comparison to the photolysis of the isolated molecules. Size distributions of different mean cluster sizes have been prepared and characterized in supersonic expansions. The clusters were photolyzed at 243 and 193 nm and the kinetic energy distributions (KEDs) of the H-fragments were measured. The KEDs of all systems exhibit a bimodal character with slow and fast H-fragment peaks similar to the spectra of the corresponding single molecules. However, with the increasing clusters size the slow component gains on intensity in comparison to the fast component. A similar effect is observed with increasing the excitation energy from 243 to 193 nm.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Week of Doctoral Students 2008
ISBN
978-80-7378-067-8
ISSN
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e-ISSN
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Number of pages
6
Pages from-to
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Publisher name
MATFYZPRESS
Place of publication
Prague
Event location
Prague
Event date
Jun 3, 2008
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
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