Acylations with Long-Chain Acid Anhydrides and Acyl Chlorides over Zeolite Beta
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F09%3A00327328" target="_blank" >RIV/61388955:_____/09:00327328 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Acylations with Long-Chain Acid Anhydrides and Acyl Chlorides over Zeolite Beta
Original language description
Acylation of ferrocene and toluene with linear, branched and aromatic anhydrides and chlorides of different chain length was investigated over zeolite Beta with Si/Al ratio 12.5. It was found that the conversion of ferrocene increased from acetic to butyric anhydride/chloride and then decreased with further increasing of chain length. The selectivity to 1-acylferrocene was in all cases 100%. In the case of toluene acylation, the conversions of acylating agent increased with the chain length of acylatingagent up to hexanoic derivatives then the conversion of acylating agent was almost constant. The selectivity to p-isomer in toluene acylation increased with the chain length. The lowest conversions in both cases were achieved with benzoic anhydride andbenzoyl chloride.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Topics in Catalysis
ISSN
1022-5528
e-ISSN
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Volume of the periodical
52
Issue of the periodical within the volume
1-2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
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UT code for WoS article
000263428100018
EID of the result in the Scopus database
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