Ligand-based Reduction in a Molecular Rectangle with Four Organplatinum(IV) Vertices

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F10%3A00341529" target="_blank" >RIV/61388955:_____/10:00341529 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Ligand-based Reduction in a Molecular Rectangle with Four Organplatinum(IV) Vertices

Original language description

A first organoplatinum(IV)-based molecular rectangle and bpyrn[{Pt(CH3)(3)}(4)(mu-eta(1):eta(1)-bp)(2)(mu-eta(2):eta(2)-bpym)(2)](4+) with bp = 4,4'-bipyridine and bpym = 2,2'-bipyrimidine has been obtained as tetrakis(triflate) in analogy to [{Re(CO)(3)}(4)(mu-eta(1):eta(1)-bp)(2)(mu-eta(2):eta(2)-bpym)(2)](4+), following the correspondence between the 5d(6) configured species [fac-Re-1(CO)(3)](+) and [fac-Pt-IV(CH3)(3)](+). Analytical data, H-1 and Pt-195 NMR spectroscopic as well as mass spectrometric results confirm the identity of the species. Cyclic voltammetry, EPR, and UV/Vis/NIR spectroelectrochemistry were used to investigate the sequence of reduction steps and the location of the electron uptake. Reduction involves first the bpym ligand in two 2-electron waves and then the bp bridge in discernible one-electron steps.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Zeitschrift für anorganische und allgemeine Chemie

ISSN

0044-2313

e-ISSN

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Volume of the periodical

636

Issue of the periodical within the volume

1

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

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UT code for WoS article

000274481500019

EID of the result in the Scopus database

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