First analysis of the high resolution FTIR spectrum of the v(2) band of the FCO2 radical at 970.2 cm(-1)

Result code in IS VaVaI

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Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

First analysis of the high resolution FTIR spectrum of the v(2) band of the FCO2 radical at 970.2 cm(-1)

Original language description

The infrared spectrum of the fluorocarboxyl radical, FCO2, was recorded at high resolution (0.0035 cm(-1)) in the 600-1400 cm(-1) region on a Bruker IFS 120 HR Fourier transform spectrometer of the University of Wuppertal. The analysis of the A-type v(2)band of FCO2 (CF stretching mode) centred at 970.208 cm(-1) was performed making use of the ground state parameters achieved by [L. Kolesnikova, J. Varga, H. Beckers, M. Simeckova, Z. Zelinger, L. Nova Striteska, P. Kania, H. Willner, and S.. Urban, J.Chem. Phys. 128, 224302/1 (2008)]. For the FCO2 radical, the v(2) transitions are, in principle, split into two spin-rotation subcomponents corresponding to J = N +/- 1/2. However the spin-rotation parameters in the 2(1) vibrational state have values similar to those of the ground state, and spin-rotation doublings are observable only for the weaker transitions involving medium K-a or K-c values in the P and R branches.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Molecular Physics

ISSN

0026-8976

e-ISSN

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Volume of the periodical

108

Issue of the periodical within the volume

6

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

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UT code for WoS article

000277031400006

EID of the result in the Scopus database

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