First analysis of the high resolution FTIR spectrum of the ?2 band of the FCO2 radical at 970.2 cm-1
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27200%2F10%3A86080237" target="_blank" >RIV/61989100:27200/10:86080237 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/00268970903514579" target="_blank" >http://dx.doi.org/10.1080/00268970903514579</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00268970903514579" target="_blank" >10.1080/00268970903514579</a>
Alternative languages
Result language
angličtina
Original language name
First analysis of the high resolution FTIR spectrum of the ?2 band of the FCO2 radical at 970.2 cm-1
Original language description
The infrared spectrum of the fluorocarboxyl radical, FCO2, was recorded at high resolution (0.0035 cm-1) in the 600-1400 cm-1 region on a Bruker IFS 120 HR Fourier transform spectrometer of the University of Wuppertal. The analysis of the A-type ?2 bandof FCO2 (CF stretching mode) centred at 970.208 cm-1 was performed taking use of the ground state parameters achieved by Kolesniková et al. [Kolesniková L, Varga J, Beckers H, Šimečková M, Zelinger Z, Nová Stříteská L, Kania P, Willner H, Urban Š. J. Chem. Phys. 128, 2008, pp. 224302-1-8]. For the FCO2 radical, the ?2 transitions are, in principle, splitted into two spin ? rotation subcomponents corresponding to J= N ?1/2. However the spin- rotation parameters in the 21 vibrational state have values similar to those of the ground state, and spin-rotation doublings are observable only for the weaker transitions involving medium Ka or Kc values in the P and R branches. The ?2 fundamental band is weakly perturbed by the 2?5 dark overtone b
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BG - Nuclear, atomic and molecular physics, accelerators
OECD FORD branch
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Result continuities
Project
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Continuities
V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular physics
ISSN
0026-8976
e-ISSN
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Volume of the periodical
108
Issue of the periodical within the volume
6
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
723-731
UT code for WoS article
000277031400006
EID of the result in the Scopus database
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