Vinyl-ruthenium entities as markers for intramolecular electron transfer processes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00361465" target="_blank" >RIV/61388955:_____/11:00361465 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2011.03.071" target="_blank" >http://dx.doi.org/10.1016/j.ica.2011.03.071</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2011.03.071" target="_blank" >10.1016/j.ica.2011.03.071</a>

Result language
angličtina
Original language name
Vinyl-ruthenium entities as markers for intramolecular electron transfer processes
Original language description
The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one ofthe two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into thecharge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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