The ground and ?6=1 vibrational levels of HC35Cl3: The first high-resolution analysis of the ?6 fundamental band
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00377501" target="_blank" >RIV/61388955:_____/12:00377501 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jqsrt.2012.01.024" target="_blank" >http://dx.doi.org/10.1016/j.jqsrt.2012.01.024</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jqsrt.2012.01.024" target="_blank" >10.1016/j.jqsrt.2012.01.024</a>
Alternative languages
Result language
angličtina
Original language name
The ground and ?6=1 vibrational levels of HC35Cl3: The first high-resolution analysis of the ?6 fundamental band
Original language description
The paper reports on the first high-resolution study of the weak ?6 fundamental rovibrational band of monoisotopic chloroform HC35Cl3. More than 4500 infrared transitions pertaining to the ?6 band have been assigned, spanning the rotational states J=0?95and 73K?K89. The new Fourier transform infrared data were combined with accurate submillimeter-wave transition frequencies in the v6=1 state measured previously [Journal of Molecular Structure 795; 2006: 157?162] in a simultaneous fit. The existence ofresonance crossings due to the View the MathML sourcel-type resonance in the v6=1 state, which generated perturbation-allowed rotational transitions, provided independent values of the C and C?6 constants. When we combined them with the wavenumbers of the fundamental ?6 band, we were able to determine accurately the axial rotational constants in the vibrational ground state C0=0.05715783 (20) cm1, View the MathML source=2.759 (63)108 cm1, and even View the MathML source=8.27 (75)1014 cm1
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/LC06071" target="_blank" >LC06071: Quasioptical Systems and Terahertz Spectroscopy</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Quantitative Spectroscopy and Radiative Transfer
ISSN
0022-4073
e-ISSN
—
Volume of the periodical
113
Issue of the periodical within the volume
11
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1220-1225
UT code for WoS article
000305355200034
EID of the result in the Scopus database
—