The v4 = 1 and v4 = 2 rovibrational levels of PF3 revisited: New solutions for old topics
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00453600" target="_blank" >RIV/61388955:_____/15:00453600 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jms.2015.07.004" target="_blank" >http://dx.doi.org/10.1016/j.jms.2015.07.004</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jms.2015.07.004" target="_blank" >10.1016/j.jms.2015.07.004</a>
Alternative languages
Result language
angličtina
Original language name
The v4 = 1 and v4 = 2 rovibrational levels of PF3 revisited: New solutions for old topics
Original language description
The high-resolution infrared spectra of trifluorophosphine (PF3) were reinvestigated in the ?4 fundamental region near 350 cm1, and around 690 cm1, with the aim to provide a necessary reassignment of the 22 sublevel of the v4 = 2 overtone level. The present paper reports on the first complete study of both sublevels of v4 = 2 (of A1 and E symmetry, corresponding to l4 = 0 and 2, respectively), through the high-resolution analysis of the overtone View the MathML source2?40 band and the View the MathML source2?42-?41 hot band. The assignments of the latter were corrected and extended, spanning the rotational states J <= 82 and 80 <= K´´ ?K <= 48. These new infrared assignments in the v4 = 2 state were combined with accurate infrared, radiofrequency, centimeter-, millimeter- and submillimeter-wave data of the v4 = 1 level (Thiessen et al., 2000), together with rotational data in the ground vibrational state (Cotti et al., 1995), in a simultaneous fit. The existence of resonance crossings
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Spectroscopy
ISSN
0022-2852
e-ISSN
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Volume of the periodical
316
Issue of the periodical within the volume
OCT 2015
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
11-21
UT code for WoS article
000361644200002
EID of the result in the Scopus database
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