Synthesis, characterization and electrochemical investigation of hetaryl chromium(0) aminocarbene complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00380421" target="_blank" >RIV/61388955:_____/12:00380421 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/12:43893577
Result on the web
<a href="http://dx.doi.org/10.1016/j.electacta.2012.05.027" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2012.05.027</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2012.05.027" target="_blank" >10.1016/j.electacta.2012.05.027</a>

Result language
angličtina
Original language name
Synthesis, characterization and electrochemical investigation of hetaryl chromium(0) aminocarbene complexes
Original language description
Fischer carbene complexes are useful precursors in organic synthesis and promising catalysts. For both these purposes, a fine ?tuning of their thermodynamic properties and reactivity is of high interest. Therefore a detailed insight into the structure?reactivity correlation is necessary for aimed design and synthesis of compounds with required specific properties. In this contribution a new series of aminocarbene complexes of chromium(0) was synthesized, where the originally used phenyl substituent in the compound I pentacarbonyl[(N,N-dimethylamino)(phenyl)carbene]chromium(0), was replaced by various five-membered heteroaromatic rings: furan (II), thiophene (III) and N-Me-pyrrol (IV), attached either by their position 2 or 3 (Fig. 1). The compounds were characterized by 1H and 13C NMR and elemental analysis. In the second part of this work an electrochemical investigation in acetonitrile followed in order to understand more deeply the oxidation and reduction process and to analyze the
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
—

Project
<a href="/en/project/IAA400400813" target="_blank" >IAA400400813: Investigation of long-distance intramolecular electronic interactions and reactivity of mono- and binuclear aminocarbene complexes using electrochemical methods</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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