Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43898141" target="_blank" >RIV/60461373:22310/14:43898141 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om500925m" target="_blank" >http://dx.doi.org/10.1021/om500925m</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om500925m" target="_blank" >10.1021/om500925m</a>
Alternative languages
Result language
angličtina
Original language name
Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten.
Original language description
Synthesis of functionalized phenyl, 2-thienyl, and N-methyl-pyrrol-2-yl Fischer carbene complexes of chromium and tungsten was achieved via a Negishi cross-coupling reaction of metalated aminocarbenes in the presence of a palladium catalyst. The reverseapproach, i.e., coupling bromocarbenes with organozinc reagents, is also feasible and is particularly useful with alkoxycarbene complexes, metalation of which is not possible. Both these procedures are also suitable for the cross-coupling of molybdenum amino- and alkoxycarbene complexes. The presented methodology enables an access to the new amino and alkoxy carbene complexes bearing aldehyde, ketone, nitrile, and ester functionality.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LC06070" target="_blank" >LC06070: The structure and synthetic applications of transition metal complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
33
Issue of the periodical within the volume
22
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
6593-6603
UT code for WoS article
000345552500039
EID of the result in the Scopus database
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