Hybrid amidinates and guanidinates of main group metals

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901643" target="_blank" >RIV/00216275:25310/16:39901643 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ccr.2015.07.012" target="_blank" >http://dx.doi.org/10.1016/j.ccr.2015.07.012</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ccr.2015.07.012" target="_blank" >10.1016/j.ccr.2015.07.012</a>

Result language
angličtina
Original language name
Hybrid amidinates and guanidinates of main group metals
Original language description
Complexes of main group metals containing amidinate and guanidinate ligands with an additional functional/donor group are reviewed. Amino-, imino-, amido-, alkoxy-, phenoxy-, carboranyl- and carbene-amidinates along with metal amidinates and a heterocyclic moiety, guanidinates(1) containing an amino group and a doubly deprotonated guanidinates reveal various structures and ligand coordination modes such as monodentate-anisobidentate-isobidentate-tridentate. The survey of chemical shifts of the central carbon atoms in C-13 NMR spectra is provided. Some of those complexes are especially applicable in ring opening polymerization of cyclic esters, lactones and polymerization of olefins.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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