Reactivity of lithium n-butyl amidinates towards group 14 metal(II) chlorides providing series of hetero- and homoleptic tetrylenes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895771" target="_blank" >RIV/00216275:25310/12:39895771 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/12:00376116
Result on the web
<a href="http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c2dt12472f" target="_blank" >http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c2dt12472f</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c2dt12472f" target="_blank" >10.1039/c2dt12472f</a>

Result language
angličtina
Original language name
Reactivity of lithium n-butyl amidinates towards group 14 metal(II) chlorides providing series of hetero- and homoleptic tetrylenes
Original language description
The new class of homo- and heteroleptic n-butyl-N,N'-disubstituted amidinato group 14 metal(II) complexes were prepared by salt elimination from starting lithium amidinates and metal(II) chlorides both in stoichiometric ratio 2 : 1 and 1 : 1, respectively. The target amidinates contain less bulky isopropyl or cyclohexyl as well as a sterically demanding aromatic substituent. Desired 1 : 1 Pb(II) complexes are not accessible by the described procedure. Ligand transfer from Pb to Sn is taking place if homoleptic Pb(II) compounds are reacted with SnCl2. Prepared tetrylenes were characterized by H-1, C-13, Sn-119 and Pb-207 NMR spectroscopy in C6D6 or THF-d(8). X-Ray diffraction studies of one heteroleptic Ge(II) monomeric where the coordination polyhedronof the three coordinated germanium atoms is a trigonal pyramid, two different dimeric structures of heteroleptic Sn(II) complexes, one amidine hydroiodide byproduct and the oxidation product of the heteroleptic chloro Sn(II) amidinate as
Czech name
—
Czech description
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Project
<a href="/en/project/GA104%2F09%2F0829" target="_blank" >GA104/09/0829: Use of Carbon Dioxide as C1 Building Block for Organic Compounds Catalyzed by Metal Containing Compounds</a>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP) S - Specificky vyzkum na vysokych skolach I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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