Oxidative Additions of Homoleptic Tin(II) Amidinate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00448340" target="_blank" >RIV/61389013:_____/15:00448340 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/15:00448340 RIV/00216275:25310/15:39900096
Result on the web
<a href="http://dx.doi.org/10.1021/om501074m" target="_blank" >http://dx.doi.org/10.1021/om501074m</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om501074m" target="_blank" >10.1021/om501074m</a>
Alternative languages
Result language
angličtina
Original language name
Oxidative Additions of Homoleptic Tin(II) Amidinate
Original language description
Seven tin(IV) amidinates were prepared and isolated from the reactions of tin(II) bisamidinate [Cy-NC(nBu)N-Cy](2)Sn with a series of various 1,2-diones ((4 + 1) oxidative cycloaddition mechanism) and chlorine/oxygen molecules, respectively. The ligand substitution effect of (non)symmetric 1,3-diones to starting stannylene as well as intermolecular CO2 activation via prepared dimeric stannoxane is also reported. All the prepared tin containing compounds as well as ligand substitution reactions were investigated by the multinuclear NMR (H-1, C-13, and Sn-119) spectroscopic techniques. Molecular structures of one tin(II) and seven tin(IV) amidinates investigated were determined by X-ray diffractions and also evaluated by DFT methods. The UV-vis absorption spectra of all desired colored tin(IV) diolates and its diketo precursors were recorded and simulated by TD-DFT methods.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
34
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
606-615
UT code for WoS article
000349273900011
EID of the result in the Scopus database
2-s2.0-84922667665