Vanadocene complexes of amino acids bearing functional group in the side chain

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896343" target="_blank" >RIV/00216275:25310/13:39896343 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0020169313002934" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0020169313002934</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2013.05.020" target="_blank" >10.1016/j.ica.2013.05.020</a>

Result language
angličtina
Original language name
Vanadocene complexes of amino acids bearing functional group in the side chain
Original language description
Reaction of Cp2VCl2 with alpha-amino acids bearing functional group in the side chain gives N,O-chelate complexes [Cp2V(N,O-aa)]Cl (aa = ser, thr, asp, glu, asn, gin, lys, arg). These complexes were studied by spectroscopic methods (EPR, IR and Raman). All prepared complexes contain amino acid ligand bonded via oxygen atom of carboxylic group and nitrogen atom of amino group in alpha-position giving five-membered chelate ring. We have observed that hydroxy, amine, carboxylic, amide and guanidinium groups present in alpha-amino acid ligand are not able to coordinate to the central vanadium atom.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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