Bis(tetra-n-butylammonium) bis[(mandelato)oxo(peroxo)-vanadate(V)] mandelic acid solvate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12640%2F00%3A00004761" target="_blank" >RIV/60076658:12640/00:00004761 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Bis(tetra-n-butylammonium) bis[(mandelato)oxo(peroxo)-vanadate(V)] mandelic acid solvate
Original language description
The crystal structure of the title complex, bis(tetra-n-butyl-ammonium) bis(mu-alpha-hydroxybenzeneacetato)-1 kappa(2)O(1),O-2:-2 kappa O-2:1 kappa O-2:2 kappa(2)O(1),O-2-bis[oxo(peroxo)vanadium(V)] alpha-hydroxybenzeneacetic acid solvate, (C16H36N)(2)[V2O2(O-2)(2)(C8K6O3)(2)]. C8H8O3, consists Of dimeric anions with twofold rotation symmetry, cations and molecules of mandelic acid. Deprotonated hydroxyl O atoms of the mandelate dianion ligands bridge the V atoms to give a non-planar V2O2 ring. Each V atom has distorted pentagonal pyramidal coordination geometry, with an oxo ligand in the axial position. The mandelic acid molecule is disordered and coordinates weakly to the second axial site of each V atom through a carboxylate O atom.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BO - Biophysics
OECD FORD branch
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Project
<a href="/en/project/VS96085" target="_blank" >VS96085: Studies of relations between function of biological membranes and interactions of their components</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2000
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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