Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010034" target="_blank" >RIV/00216224:14310/04:00010034 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Peroxovanadium(V) complexes of -hydroxyhippuric acid. The X-ray crystal structure of (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)]
Original language description
Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O [M=NMe4+ (1), NPr4+ (2); n=0.5, 5], have been prepared and characterized by elemental analysis and by IR and Raman spectroscopies. The X-ray crystalstructure of 2 has been determined as the first crystal structure of an -hydroxyhippurato complex. A single crystal X-ray diffraction study has shown that the -hhip ligand behaves as a tridentate chelator adopting the (O-, COO-, CO) donor set. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.
Czech name
Peroxovanadičnatý komplex kyseliny alfa-hydroxyhipurité. RTG struktura (NPr4)2[V2O2(O2)2(alpha-hhip)2] .5H2O, [alpha-hhip=alpha-hydroxyhippurato (2-) - C9H7NO4 (2-)].
Czech description
Peroxovanadičnatý komplex s kyselinou alfa-hydroxyhipuritou byl syntetizován a charakterizován element. analýzou, IR a Raman. spektroskopií a RTG trukturní analýzou. Jde o první RTG strukturu komplexu s touto kyselinou.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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