Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010671" target="_blank" >RIV/00216224:14310/04:00010671 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Synthesis and characterization of vanadium(V) complexes with alpha-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)]
Original language description
Peroxovanadium(V) complexes of alpha-hydroxyhippuric acid (alpha-H2hhip), M2[V2O2(O2)2(alpha-hhip)2].nH2O, [M=K+(1), NH4+(2), NEt4+(3), NBu4+(4); n=5.5, 3, 8, 5) have been prepared and characterized by elemental analysis, i.r., u.v.-vis. and 51V-n.m.r. spectroscopies and by thermal analysis. The X-ray structure determination of (4) revealed the presence of dinuclear [V2O2(O2)2(R-alpha-hhip)(S-alpha-hhip)]2- anions with a planar V2O2 bridging core and seven-coordinated central atoms. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.
Czech name
Syntéza a charakterizace vanadičného komplexu s kyselinou alpha-hydroxyhippuriktovou . Krystalová struktura (NBu4)2[V2O2(O2)2(R-alpha-hhip) (S--hhip)].5H2O,[alpha-hhip = alpha-hydroxyhippurato(2-)].
Czech description
Peroxovanadičnatý komplex s s kyselinou alpha-hydroxyhippuriktovou byl připraven a charakterizován elemental analýzou, IR , UV-VIS a 51V-NMR spektroskopickými technikami, termál. analýzou a RTG difrakcí.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Transition Metal Chemistry
ISSN
0340-4285
e-ISSN
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Volume of the periodical
29
Issue of the periodical within the volume
6
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
675-680
UT code for WoS article
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EID of the result in the Scopus database
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