Synthesis and Catalytic Activity of [CpCo(COD)] Complexes Bearing Pendant N-Containing Groups

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00392930" target="_blank" >RIV/61388955:_____/13:00392930 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om400330x" target="_blank" >http://dx.doi.org/10.1021/om400330x</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om400330x" target="_blank" >10.1021/om400330x</a>

Result language
angličtina
Original language name
Synthesis and Catalytic Activity of [CpCo(COD)] Complexes Bearing Pendant N-Containing Groups
Original language description
The novel Co(I)-complex [CpCNCo(COD)] (CpCN = ?5-(C5H4CMe2CH2CN), COD = 1,5-cyclooctadiene; 3) with a substituted cyclopentadienyl ligand containing a pendant nitrile moiety has been synthesized and characterized by X-ray diffraction. The reactivity of the nitrile group in 3 has been investigated regarding its behavior in cyclization reactions with alkynes, leading to three new complexes containing pendant 2-pyridyl groups. All synthesized complexes have been evaluated as catalysts in the [2 + 2 + 2] cycloaddition reaction of 1,6-heptadiyne and benzonitrile.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GPP207%2F10%2FP200" target="_blank" >GPP207/10/P200: Complexes of Group 4 Elements Containing Cyclopentadienyl Ligands with Pendant Unsaturated Bonds: Synthesis and Reactivity</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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