Catalytic performance of Metal-Organic-Frameworks vs.extra-large porezeolite UTL in condensation reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00421160" target="_blank" >RIV/61388955:_____/13:00421160 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.3389/fchem.2013.00011" target="_blank" >http://dx.doi.org/10.3389/fchem.2013.00011</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3389/fchem.2013.00011" target="_blank" >10.3389/fchem.2013.00011</a>
Alternative languages
Result language
angličtina
Original language name
Catalytic performance of Metal-Organic-Frameworks vs.extra-large porezeolite UTL in condensation reactions
Original language description
Catalytic behavior of isomorphously substituted B-, Al-, Ga-, and Fe-containing extra-large pore UTL zeolites was investigated in Knoevenagel condensation involving aldehydes, Pechmann condensation of 1-naphthol with ethylacetoacetate, and Prins reactionof ?-pinene with formaldehyde and compared with large-pore aluminosilicate zeolite beta and representative Metal-Organic-Frameworks Cu3(BTC)2 and Fe(BTC). The yield of the target product over the investigated catalysts in Knoevenagel condensation increases in the following sequence: (Al)beta < (Al)UTL < (Ga)UTL < (Fe)UTL < Fe(BTC) < (B)UTL < Cu3(BTC)2 being mainly related to the improving selectivity with decreasing strength of active sites of the individual catalysts. The catalytic performance of Fe(BTC), containing the highest concentration of Lewis acid sites of the appropriate strength is superior over large-pore zeolite (Al)beta and B-, Al-, Ga-, Fe-substituted extra-large pore zeolites UTL in Prins reaction of ?-pinene with forma
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Frontiers in Chemistry
ISSN
2296-2646
e-ISSN
—
Volume of the periodical
1
Issue of the periodical within the volume
AUG 2013
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
—
UT code for WoS article
—
EID of the result in the Scopus database
—