Superior Performance of Metal?Organic Frameworks over Zeolites as Solid Acid Catalysts in the Prins Reaction: Green Synthesis of Nopol

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00392528" target="_blank" >RIV/61388955:_____/13:00392528 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1002/cssc.201300032" target="_blank" >http://dx.doi.org/10.1002/cssc.201300032</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cssc.201300032" target="_blank" >10.1002/cssc.201300032</a>

Result language

angličtina

Original language name

Superior Performance of Metal?Organic Frameworks over Zeolites as Solid Acid Catalysts in the Prins Reaction: Green Synthesis of Nopol

Original language description

The catalytic performance of a set of metal?organic frameworks [CuBTC, FeBTC, MIL-100(Fe), MIL-100(Cr), ZIF-8, MIL-53(Al)] was investigated in the Prins condensation of b-pinene with formaldehyde and compared with the catalytic behavior of conventional aluminosilicate zeolites BEA and FAU and titanosilicate zeolite MFI (TS-1). The activity of the investigated metal?organic frameworks (MOFs) increased with the increasing concentration of accessible Lewis acid sites in the order ZIF-8<MIL-53(Al)<FeBTC<MIL-100(Cr)<MIL-100(Fe). Unwanted b-pinene-like isomerization takes place on the strong Br?nsted acid sites of zeolites BEA and FAU, which showed significantly lower selectivity to the target nopol than the MOFs. Its high activity, the preservation of its structure and active sites, and the possibility to use it in at least three catalytic cycles without loss of activity make MIL-100 (Fe) the best performing catalyst of the series for the Prins condensation of b-pinene and paraformaldehyde.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ChemSusChem

ISSN

1864-5631

e-ISSN

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Volume of the periodical

6

Issue of the periodical within the volume

5

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

865-871

UT code for WoS article

000318356000015

EID of the result in the Scopus database

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