Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00473610" target="_blank" >RIV/61388955:_____/17:00473610 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/17:10368341
Result on the web
<a href="http://dx.doi.org/10.1002/cplu.201600456" target="_blank" >http://dx.doi.org/10.1002/cplu.201600456</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.201600456" target="_blank" >10.1002/cplu.201600456</a>
Alternative languages
Result language
angličtina
Original language name
Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type
Original language description
The catalytic behavior of isomorphously substituted MIL-100(M) (M=Al, Cr, Fe, In, Sc, V) is investigated for the synthesis of nopol through the Prins condensation ofpinene with paraformaldehyde. The large mesoporous cages of the metal-organic frameworks provide a sustainable confinement for the formation of the target product (100% selectivity for nopol over all materials studied). MIL-100(Sc) and MIL-100(V) exhibit the highest yields (up to 90%) of nopol after just 20min from the beginning of the reaction, owing to their high concentrations of accessible Lewis sites possessing intermediate acidity. The high catalytic activity (reaching almost 90%pinene conversion) even upon decreasing the amount of catalyst from 100 to 25mg (0.025 and 0.0063g(catalyst)mmol(substrate)(-1), respectively), the stability of its structure, and the possibility to use it several times, make MIL-100(V) a promising material for applications in acid-catalyzed reactions under mild reaction conditions.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA14-07101S" target="_blank" >GA14-07101S: Combined Experimental and Theoretical Investigation of Catalytic Properties of Metal Organic Frameworks</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
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Volume of the periodical
82
Issue of the periodical within the volume
1
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
152-159
UT code for WoS article
000394182400014
EID of the result in the Scopus database
2-s2.0-84995378019